Development and validation of voltammetric method to determination of bisphenol A in drinking water samples

Mercado, Yomenson Bello; Morais, Amanda; Almeida, Sthéfane Valle de; Lima, Camila Alves de; Lopes, Mauro Chierici; Felsner, Maria Lurdes; Galli, Andressa

Acessibilidade / Reportar erro

Brasil

Español English

sumário « anterior atual seguinte »

Sumário

Artigos • Matéria (Rio J.) 29 (2) • 2024 • https://doi.org/10.1590/1517-7076-rmat-2023-0371 copy

Development and validation of voltammetric method to determination of bisphenol A in drinking water samples

Authorship SCIMAGO INSTITUTIONS RANKINGS

ABSTRACT

The bisphenol A (BPA) is a raw material in plastic manufacturing and is known as an endocrine disruptor. The development and validation of a voltammetric method for BPA determination were carried out, based on disposable carbon sensors modified with carbon black. Square-wave voltammetry was selected for BPA determination in mineral water samples, marketed in plastic bottles, and this method was validated using figures of merit. A linear response was observed in the concentration range of 6.10 to 27.4 µmol L^–1, with detection and quantification limits values of 0.137 µmol L^–1 and 0.416 µmol L^–1, respectively. The method demonstrated adequate selectivity and good precision, with relative standard deviations ranging from 0.59 to 9.89%, which were below the indicated limit for this concentration range. Accuracy estimation, in terms of average recovery, ranged from 58.16 to 118.79%, falling within the limits established by regulatory agencies. Thus, the results obtained in this study are viable compared to other studies reported in the literature for BPA determination, presenting themselves as a rapid and cost-effective alternative for monitoring this contaminant.

Keywords
Bisphenol A; Square Wave Voltammetry; Screen Printed Electrode; Carbon Black

SENSOR	MATRIZ	LD (µmol L^–1)	LQ (µmol L^–1)	REFERÊNCIA
DPNs/AuNPs/SPCE	Água de torneira	0,00663	Não reportado	[²⁶[26] KARIMI‐MALEH, H., KARIMI, F., ALIZADEH, M., et al., “Electrochemical sensors, a bright future in the fabrication of portable kits in analytical systems.”, Chemical Record (New York, N.Y.), v. 20, n. 7, pp. 682–692, 2020. doi: http://dx.doi.org/10.1002/tcr.201900092. PubMed PMID: 31845511. https://doi.org/10.1002/tcr.201900092... ]
Lacase/PANI/SPE	Água residual	0,000438 (0,1 ppb)	Não reportado	[⁴⁹[49] JO, E., LEE, J., “Polyaniline-nanofiber-modified screen-printed electrode with intermediate dye amplification for detection of endocrine disruptor Bisphenol A.”, Microchemical Journal, v. 155, pp. 104693, 2020. doi: http://dx.doi.org/10.1016/j.microc.2020.104693. https://doi.org/10.1016/j.microc.2020.10... ]
CdTe@QDs-FG-PEDOT:PSS/SPE	Água de rio	0,034	Não reportado	[⁵⁰[50] SANTOS, A.M., FEITOSA, M.H.A., WONG, A., et al., “Functionalized graphene, quantum dots, and PEDOT:PSS based screen-printed electrode for the endocrine disruptor Bisphenol A determination.”, Sensors and Actuators. B, Chemical, v. 399, pp. 134745, 2024. doi: http://dx.doi.org/10.1016/j.snb.2023.134745. https://doi.org/10.1016/j.snb.2023.13474... ]
MAC-Co-SPE	Água de rio Água mineral Água de torneira	0,010	0,033	[⁵¹[51] EMAMBAKHSH, F., ASADOLLAHZADEH, H., RASTAKHIZ, N., et al., “Highly sensitive determination of Bisphenol A in water and milk samples by using magnetic activated carbon - cobalt nanocomposite-screen printed electrode.”, Microchemical Journal, v. 179, pp. 107466, 2022. doi: http://dx.doi.org/10.1016/j.microc.2022.107466. https://doi.org/10.1016/j.microc.2022.10... ]
La³⁺ dopado com Co₃O₄/SPE	Água de rio Água mineral Água de torneira	0,061	0,18	[⁵²[52] BEITOLLAHI, H., MAHMOUDI MOGHADDAM, H., TAJIK, S., “Voltammetric determination of bisphenol a in water and juice using a Lanthanum (III)-Doped Cobalt (II,III) Nanocube modified carbon screen-printed electrode.”, Analytical Letters, v. 52, n. 9, pp. 1432–1444, 2019. doi: http://dx.doi.org/10.1080/00032719.2018.1545132. https://doi.org/10.1080/00032719.2018.15... ]
GDY-cMWCNT/SPE	Água de lago	0,013	Não reportado	[⁵³[53] HE, S., XIA, H., CHANG, F., “Enzyme free electrochemical determination of bisphenol a using screen-printed electrode modified by graphdiyne and carbon nanotubes.”, Microchemical Journal, v. 182, pp. 107858, 2022. doi: http://dx.doi.org/10.1016/j.microc.2022.107858. https://doi.org/10.1016/j.microc.2022.10... ]
SPCE/CB	Água mineral	0,732	1,701	Este trabalho

AMOSTRA	EQUAÇÃo DA RETA	LD µmol L^–1	LQ µmol L^–1
Amostra 1	–0,50 + 0,06 [BPA]	0,39	0,90
Amostra 2	–0,41 + 0,06 [BPA]	0,37	0,86
Amostra 3	–0,14 + 0,03 [BPA]	1,44	3,35

AMOSTRA	BPA ADICIONADO µmol L^–1	REPETIBILIDADE DPR%	PRECISÃO INTERMEDIÁRIA DPR%	ECUPERAÇÃO %
Eletrólito puro	12,2	3,48	9,89	84,77
	21,3	0,59	1,33	109,35
	27,4	1,83	3,48	95,81
Amostra 1	12,2	3,21	3,89	88,18
	21,3	2,75	3,73	116,86
	27,4	3,85	4,14	92,14
Amostra 2	12,2	3,65	3,07	93,16
	21,3	1,81	2,78	109,76
	27,4	1,32	1,86	95,45
Amostra 3	12,2	1,57	3,39	93,05
	21,3	2,64	3,06	109,88
	27,4	1,53	2,07	95,38

Laboratório de Hidrogênio, Coppe - Universidade Federal do Rio de Janeiro, em cooperação com a Associação Brasileira do Hidrogênio, ABH2 Av. Moniz Aragão, 207, 21941-594, Rio de Janeiro, RJ, Brasil, Tel: +55 (21) 3938-8791 - Rio de Janeiro - RJ - Brazil
E-mail: revmateria@gmail.com

Acompanhe os números deste periódico no seu leitor de RSS

[1] Autor Responsável: Andressa Galli.

Faixa linear (µmol L^–1)			6,1–27,4
Regressão	Falta de ajuste	r	*R²(%)*
^* Fcrítico(0,05;1,16)= 4,49 F _regressão p*	^ Fcrítico(0,05;4,12) = 3,26 F _{falta de ajuste} p	0,955	91,2
342,70 0,000	0,67 0,0000
Coeficiente da reta ± erro padrão		^* tcrítico(0.05;1,16)= 2,119 t _observado*	p
Intercepto: –0,167 ± 0,0491		3,39	0,004
Inclinação: 0,0240 ± 0,00272		18,51	0,000